Propylene glycol ethers (88917-22-0 & 55934-93-5)

Project ID

2818

Category

OPPT

Added on

July 2, 2019, 11:49 a.m.

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Journal Article

Abstract  The appropriate combination of viscosifier and coviscosifier is a very important factor in the control of the viscosity and adhesion properties of chemical decontamination gels. A chemical decontamination gel was prepared by adding gelling agents composed of a pyro Si viscosifier and PEG-based non-ionic coviscosifier (tripropylene glycol butyl ether and tripropylene glycol dodecyl ether) into a Ce(IV) solution stabilized in concentrated nitric acid. The decontamination and rheological behaviours, along with the drying behaviours of a chemical gel for SUS 304 metallic surfaces contaminated with Co and Cs radionuclides were investigated. A chemical gel containing a 0.5 wt % tripropylene glycol dodecyl ether coviscosifier was more effective in terms of the rheological and drying-detachment properties and the radionucleide decontamination effectiveness in particular, compared to tripropylene glycol butyl ether.

Journal Article

Abstract  The addition of oxygen-bearing compounds to diesel fuel considerably reduces particulate emissions. TGME and DBM have been identified as possible diesel additives based on their physicochemical characteristics and performance in engine tests. Although these compounds will reduce particulate emissions, their potential environmental impacts are unknown. As a means of characterizing their persistence in environmental media such as soil and groundwater, we conducted a series of biodegradation tests of DBM and TGME. Benzene and methyl tertiary butyl ether (MTBE) were also tested as reference compounds. Primary degradation of DBM fully occurred within 3 days, while TGME presented a lag phase of approximately 8 days and was not completely degraded by day 28. Benzene primary degradation occurred completely by day 3 and MTBE did not degrade at all. The total mineralized fractions of DBM and TGME achieved constant values as a function of time of approximately 65% and approximately 40%, respectively. Transport predictions show that, released to the environment, DBM and TGME would concentrate mostly in soils and waters with minimal impact to air. From an environmental standpoint, these results combined with the transport predictions indicate that DBM is a better choice than TGME as a diesel additive.

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