Electrochemical generation of glycosyl triflate pools
Nokami, T; Shibuya, A; Tsuyama, H; Suga, S; Bowers, AA; Crich, D; Yoshida, J
HERO ID
1045524
Reference Type
Journal Article
Year
2007
Language
English
PMID
| HERO ID | 1045524 |
|---|---|
| In Press | No |
| Year | 2007 |
| Title | Electrochemical generation of glycosyl triflate pools |
| Authors | Nokami, T; Shibuya, A; Tsuyama, H; Suga, S; Bowers, AA; Crich, D; Yoshida, J |
| Journal | Journal of the American Chemical Society |
| Volume | 129 |
| Issue | 35 |
| Page Numbers | 10922-10928 |
| Abstract | Glycosyl triflates, which serve as important intermediates in glycosylation reactions, were generated and accumulated by the low-temperature electrochemical oxidation of thioglycosides such as thioglucosides, thiogalactosides, and thiomannosides in the presence of tetrabutylammonium triflate (Bu(4)NOTf) as a supporting electrolyte. Thus-obtained solutions of glycosyl triflates (glycosyl triflate pools) were characterized by low-temperature NMR measurements. The thermal stability of glycosyl triflates and their reactions with glycosyl acceptors were also examined. |
| Doi | 10.1021/ja072440x |
| Pmid | 17696345 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Is Qa | No |