Different properties of electrospun fibrous scaffolds of separated heavy-chain and light-chain fibroins of Bombyx mori

Wadbua, P; Promdonkoy, B; Maensiri, S; Siri, S

HERO ID

1053877

Reference Type

Journal Article

Year

2010

Language

English

PMID

20338193

HERO ID 1053877
In Press No
Year 2010
Title Different properties of electrospun fibrous scaffolds of separated heavy-chain and light-chain fibroins of Bombyx mori
Authors Wadbua, P; Promdonkoy, B; Maensiri, S; Siri, S
Journal International Journal of Biological Macromolecules
Volume 46
Issue 5
Page Numbers 493-501
Abstract This study is the first to report on the fabrication and properties of electrospun scaffolds derived from separated light-chain fibroin and heavy-chain fibroin, two major proteins of silk fibroin. Among seven different extraction conditions, which were commonly used to extract fibroin from cocoons of Bombyx mori, only Ajisawa's reagent and 9 M lithium thiocyanate could extract both heavy-chain fibroin and light-chain fibroin, while the other conditions could yield only the light-chain fibroin. Mixed fibroin, light-chain fibroin, and heavy-chain fibroin were fabricated using electrospinning methods. Average diameters of the fibers were 658+/-208, 517+/-162, and 518+/-171 nm, respectively and their sizes after treatment with 50% methanol for 60 min were slightly increased to 747+/-244, 556+/-164 and 521+/-201 nm, respectively. FTIR spectra showed similar predominant beta-sheet conformation of mixed fibroin and heavy-chain fibroin scaffolds after treated with methanol, whereas the predominant structure of light-chain fibroin was random coil conformation. Although, scaffolds derived from mixed fibroin and heavy-chain fibroin showed similar properties, the light-chain fibroin scaffold clearly exhibited different properties, including more hydrophilic character, water uptake ability, degradation rate, and cell adhesion capability.
Doi 10.1016/j.ijbiomac.2010.03.007
Pmid 20338193
Wosid WOS:000278586200005
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000278586200005
Is Public Yes
Language Text English
Keyword Electrospinning; Nanofiber; Light-chain fibroin; Heavy-chain fibroin
Is Qa No