Brominated flame retardants in dust from UK cars--within-vehicle spatial variability, evidence for degradation and exposure implications

Harrad, S; Abdallah, MA

HERO ID

1082335

Reference Type

Journal Article

Year

2011

Language

English

PMID

21208641

HERO ID 1082335
In Press No
Year 2011
Title Brominated flame retardants in dust from UK cars--within-vehicle spatial variability, evidence for degradation and exposure implications
Authors Harrad, S; Abdallah, MA
Journal Chemosphere
Volume 82
Issue 9
Page Numbers 1240-1245
Abstract Polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDs), and tetrabromobiphenol-A (TBBP-A) were measured in a preliminary study of dust from passenger cabins and trunks of 14 UK cars. Concentrations in cabin dust of HBCDs, TBBP-A, and BDEs 47, 85, 99, 100, 153, 154, 183, 196, 197, 202, 203, 206, 207, 208, and 209 exceeded significantly (p<0.05) those in trunk dust. Sampling cabin dust thus appears to provide a more accurate indicator of human exposure via car dust ingestion than trunk dust. Elevated cabin concentrations are consistent with greater in-cabin use of BFRs. In five cars, while no significant differences (p>0.05) in concentrations of HBCDs and most PBDEs were detected in dust sampled from four different seating areas; concentrations of TBBP-A and of PBDEs 154, 206, 207, 208, and 209 were significantly higher (p<0.05) in dust sampled in the front seats. Possible photodebromination of BDE-209 was indicated by significantly higher (p<0.05) concentrations of BDE-202 in cabin dust. In-vehicle exposure via dust ingestion to PBDEs, HBCDs and TBBP-A exceeded that via inhalation. Comparison with overall exposure via diet, dust ingestion, and inhalation shows while in-vehicle exposure is a minor contributor to overall exposure to BDE-99, ΣHBCDs, and TBBP-A, it is a significant pathway for BDE-209.
Doi 10.1016/j.chemosphere.2010.12.038
Pmid 21208641
Wosid WOS:000287563200004
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Dust; Cars; PBDEs; HBCDs; Degradation; Human exposure
Relationship(s)