High-pressure isobaric heat capacities using a new flow calorimeter

Segovia, JJ; Vega-Maza, D; Chamorro, CR; Martin, MC

HERO ID

1136249

Reference Type

Journal Article

Year

2008

HERO ID 1136249
In Press No
Year 2008
Title High-pressure isobaric heat capacities using a new flow calorimeter
Authors Segovia, JJ; Vega-Maza, D; Chamorro, CR; Martin, MC
Journal Journal of Supercritical Fluids
Volume 46
Issue 3
Page Numbers 258-264
Abstract An automated flow calorimeter has been developed for the measurement of high accurate isobaric heat capacities for pure compounds and mixtures over the range 250-400 K and 0-20 MPa. The technique has been checked for different compounds and at different conditions of temperature and pressure and the results have been compared with the literature values available. The conclusion of this comparison is that the new calorimeter can measure heat capacities with an estimated total uncertainty better than 0.5%. This paper report describes the new equipment, its set-up and gives new heat capacity data for toluene and ethyl tert-butyl ether at different temperatures and pressures. (C) 2008 Elsevier B.V. All rights reserved.
Doi 10.1016/j.supflu.2008.01.011
Wosid WOS:000259464700008
Url http://linkinghub.elsevier.com/retrieve/pii/S0896844608000132
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000259464700008
Is Public Yes
Keyword isobaric heat capacity; high pressure; toluene; ETBE; flow calorimeter
Is Qa No