Thermodynamics of fuels with a biosynthetic component. II. Vapor-liquid equilibrium data for binary and ternary mixtures containing ethyl 1,1-dimethylethyl ether, 1-hexene, and cyclohexane at T=313.15 K

Villamanan, RM; Vega-Maza, D; Chamorro, CR; Villamanan, MA; Segovia, J

HERO ID

1249208

Reference Type

Journal Article

Year

2008

Language

English

HERO ID 1249208
In Press No
Year 2008
Title Thermodynamics of fuels with a biosynthetic component. II. Vapor-liquid equilibrium data for binary and ternary mixtures containing ethyl 1,1-dimethylethyl ether, 1-hexene, and cyclohexane at T=313.15 K
Authors Villamanan, RM; Vega-Maza, D; Chamorro, CR; Villamanan, MA; Segovia, J
Journal Journal of Chemical and Engineering Data
Volume 53
Issue 1
Page Numbers 247-251
Abstract Vapor-liquid equilibria, data containing ethyl 1, 1-dimethylethyl ether (ETBE) as an ether synthesized from ethanol of biological origin, are presented giving isothermal p-x-y data for the ternary system ethyl 1, 1 dimethylethyl ether (ETBE) + 1-hexene + cyclohexane and the two binary systems involved containing the ether at 313.15 K. A static technique consisting of an isothermal total pressure cell was used for the measurements. Data reduction by Barker's method provides correlations for G, using the Margules equation for the binary systems and the Wohl expansion for the ternary system. Wilson, NRTL, and UNIQUAC models have also been alied to both binary and ternary systems. The mixtures measured exhibit a slight positive deviation from ideal behavior.
Doi 10.1021/je7005488
Wosid WOS:000252292600045
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000252292600045
Is Public Yes
Language Text English
Keyword TOTAL-PRESSURE DATA; SUBSTITUTION HYDROCARBONS; PLUS CYCLOHEXANE; N-HEPTANE; SYSTEMS; EXPRESSION; REDUCTION; ENERGY; HEXANE; GE
Is Qa No