Solubility of hyperbranched polymer, Boltorn W-3000, in alcohols, ethers and hydrocarbons
Domańska, U; Żołek-Tryznowska, Z
| HERO ID | 1293082 |
|---|---|
| In Press | No |
| Year | 2010 |
| Title | Solubility of hyperbranched polymer, Boltorn W-3000, in alcohols, ethers and hydrocarbons |
| Authors | Domańska, U; Żołek-Tryznowska, Z |
| Journal | Journal of Chemical Thermodynamics |
| Volume | 42 |
| Issue | 10 |
| Page Numbers | 1304-1309 |
| Abstract | (Solid/liquid + liquid) phase diagrams at ambient pressure have been determined for the hyperbranched polymer, Boltorn W3000 with alcohols (methanol, ethanol, 1-propanol, 1-hexanol, 1-decanol), or with ethers (tert-butyl methyl ether, tert-butyl ethyl ether), or with hydrocarbons (n-hexane, n-heptane, benzene, toluene) by a dynamic method from T = 240 K to the boiling temperature of the solvent. (Solid + liquid) phase equilibria with immiscibility in the liquid phase were detected for B-W3000 with the alcohols and aliphatic hydrocarbons. The upper critical solution temperatures, UCSTs, were measured for (B-W3000 + 1-hexanol and 1-decanol) systems. The experimental results of (solid + liquid) phase equilibria have been correlated using NRTL equation. © 2010 Elsevier Ltd. All rights reserved. |
| Doi | 10.1016/j.jct.2010.05.013 |
| Wosid | WOS:000280396300018 |
| Url | http://linkinghub.elsevier.com/retrieve/pii/S0021961410001783 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | Hyperbranched polymer; (Solid/liquid plus liquid) phase equilibria; Correlation; Molecular interactions |