Characterization of genotoxic components in sediments by mass spectrometric techniques combined with Salmonella microsome test

Grifoll, M; Solanas, AM; Bayona, JM

HERO ID

1333463

Reference Type

Journal Article

Year

1990

Language

English

PMID

2322018

HERO ID 1333463
In Press No
Year 1990
Title Characterization of genotoxic components in sediments by mass spectrometric techniques combined with Salmonella microsome test
Authors Grifoll, M; Solanas, AM; Bayona, JM
Journal Archives of Environmental Contamination and Toxicology
Volume 19
Issue 2
Page Numbers 175-184
Abstract BIOSIS COPYRIGHT: BIOL ABS. The application of Salmonella/microsomal mammalian tests to column chromatography fractions isolated from river and marine sediments collected in the vicinity of Barcelona City, Spain, demonstrated a positive response (TA98+S9 mix) among the polar fractions. Chemical analysis by high resolution gas chromatography coupled to negative ion chemical ionization mass spectrometry (HRGC-NICI MS) provided sensitivity and selectivity to detect several mutagenic chemical classes. Among them, nitrated PAHs, azaarenes, aromatic amines, anhydrides, and ketones were identified. A total of 116 compounds were tentatively identified, 22 for the first time, of which 16 possessed mutagenic activity. However, a lack of correlation between chemical composition and fraction mutagenicity in the medium polarity fractions, especially in the river sediment, was evidenced. The occurrence of multiple interactions between components in spiked organic extracts is demonstrated.
Doi 10.1007/BF01056084
Pmid 2322018
Url https://doi.org/10.1007/BF01056084
Is Certified Translation No
Dupe Override 1333463
Is Public Yes
Language Text English
Keyword <?xml version="1.0" encoding="UTF-8"?><kw>Genetics and Cytogenetics-General</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Ecology</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Ecology</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Ecology</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Biochemical Methods-Nucleic Acids</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Toxicology-Environmental and Industrial Toxicology</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Genetics of Bacteria and Viruses</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Microbiological Apparatus</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Public Health: Environmental Health-Air</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Soil Science-Physics and Chemistry (1970- )</kw>; <?xml version="1.0" encoding="UTF-8"?><kw>Enterobacteriaceae (1979- )</kw>
Relationship(s)