Complexes of rhodium(III) with N-functionalized calix[4]resorcinolol
Guseva, EV; Morozov, VI; Zinkicheva, TT; Voloshina, AD; Grishin, EI
| HERO ID | 1543958 |
|---|---|
| In Press | No |
| Year | 2012 |
| Title | Complexes of rhodium(III) with N-functionalized calix[4]resorcinolol |
| Authors | Guseva, EV; Morozov, VI; Zinkicheva, TT; Voloshina, AD; Grishin, EI |
| Journal | Russian Journal of General Chemistry |
| Volume | 82 |
| Issue | 8 |
| Page Numbers | 1323-1333 |
| Abstract | Singularities of the rhodium trichloride reaction with calix[4]resorcinol functionalized with CH2N center dot (CH3)(2) groups in ethanol on the upper rim of the molecule, and also of calix[4]resorcinol with ethanol solution of rhodium trichloride saturated with nitrogen monoxide were studied. Neutral complex compounds separated in the solid form were characterized by IR spectroscopy, Raman spectroscopy, H-1 NMR, ESR, X-ray electron spectroscopy, electronic spectroscopy, and conductometry. Quantum-chemical calculations were performed on the basis of the density functional method in order to determine the geometric structure and energy characteristics of the complex compound and the zwitter-ion form of the ligand. |
| Doi | 10.1134/S1070363212080014 |
| Wosid | WOS:000308820000001 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science WOS:000308820000001 |
| Is Public | Yes |