Poly[di-μ-chlorido-μ-(1,2,3,9-tetra-hydro-pyrrolo-[2,1-b]quinazolin-9-one-κN:O)-mercury(II)]
Turgunov, KK; Wang, Y; Englert, U; Shakhidoyatov, KM
HERO ID
1553967
Reference Type
Journal Article
Year
2011
Language
English
PMID
| HERO ID | 1553967 |
|---|---|
| In Press | No |
| Year | 2011 |
| Title | Poly[di-μ-chlorido-μ-(1,2,3,9-tetra-hydro-pyrrolo-[2,1-b]quinazolin-9-one-κN:O)-mercury(II)] |
| Authors | Turgunov, KK; Wang, Y; Englert, U; Shakhidoyatov, KM |
| Journal | Acta Crystallographica. Section E: Structure Reports Online |
| Volume | 67 |
| Issue | Pt 7 |
| Page Numbers | m953-m954 |
| Abstract | In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one mol-ecule of the quinazoline unit. Pseudo-octa-hedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre leading to different Hg-Cl bonds (short and long) and linked by other Cl atoms via translation along the a axis. The quinazoline ligands connect the Hg-Cl-Hg-Cl chains by N and O atoms along the b axis, forming the two-dimensional network structure. The crystal structure is stabilized by weak non-classical C-H⋯Cl hydrogen bonds and aromatic π-π stacking inter-actions [centroid-centroid distances = 3.942 (4) and 3.621 (4) Å]. |
| Doi | 10.1107/S1600536811022471 |
| Pmid | 21836934 |
| Wosid | WOS:000294663000102 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |