Adsorbate induced reconstruction of cobalt surfaces
Ciobica, IM; van Santen, RA; van Berge, PJ; de Loosdrecht, J
| HERO ID | 1656292 |
|---|---|
| In Press | No |
| Year | 2008 |
| Title | Adsorbate induced reconstruction of cobalt surfaces |
| Authors | Ciobica, IM; van Santen, RA; van Berge, PJ; de Loosdrecht, J |
| Journal | Surface Science |
| Volume | 602 |
| Issue | 1 |
| Page Numbers | 17-27 |
| Abstract | Coverage dependence adsorption of intermediates typical for syngas conversion is studied theoretically on FCC-cobalt surfaces. The FCC structure is relevant for cobalt particles active in this reaction. Emphasis on the analysis is on the thermodynamics of surface reconstruction as a function of surface adsorbate and surface coverage. An important result is the finding that only adsorbed carbon induced reconstruction of FCC-CO(1 1 1) to FCC-CO(1 0 0) as well as the clock reconstruction for the two surfaces. (C) 2007 Elsevier B.V. All rights reserved. |
| Doi | 10.1016/j.susc.2007.09.060 |
| Wosid | WOS:000252904700006 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science WOS:000252904700006 |
| Is Public | Yes |
| Keyword | chemisorption; surface reconstruction; FCC-cobalt surfaces |