Metabolism and excretion of 2,4,5,2',5'-pentachlorobiphenyl (PCB) in male rat

Chen, PR; Matthews, HB

HERO ID

2157179

Reference Type

Journal Article

Subtype

Abstract

Year

1974

Language

English

HERO ID 2157179
Material Type Abstract
In Press No
Year 1974
Title Metabolism and excretion of 2,4,5,2',5'-pentachlorobiphenyl (PCB) in male rat
Authors Chen, PR; Matthews, HB
Journal Toxicology and Applied Pharmacology
Volume 29
Issue 1
Page Numbers 88
Abstract The metabolism and excretion of [14C]PCB in male rats was followed as part of a pharma­ cokinetic study. After iv doses of 0.6 or 6.0 mg/kg, excretion of PCB occurred primarily in the feces of rats with about 50% excreted during the first 3 days after dosing. Another 12% was excreted in feces during the next 4 days. About 5% of the dose of PCB was excreted in the urine during the first 24 hr with only an additional 1% excreted thereafter. Analysis of radio­ activity excreted in the feces revealed the presence of 2 metabolites as well as significant amounts of parent PCB. Both metabolites were isolated and analyzed by chemical ionization mass spectroscopy (MS). The data obtained from MS indicated the major metabolite was a mono­ hydroxylated-PCB and the minor metabolite was a dihydroxy analog. NMR studies are in progress to determine the positions of the hydroxyl groups. Analysis of urinary radioactivity revealed the presence of only 1 metabolite, a glucuronide conjugate. That metabolism is closely coupled to excretion is suggested by the fact that no metabolites of PCB were found in liver and other tissues. The size of the dose apparently had no effect on the rate of excretion. During the first 24 hr, the rate of excretion of PCB and metabolites in the feces was markedly increased by animal pretreatment with an inducer, phenobarbital, and decreased by an inhibitor, SKF-525A, of the hepatic microsomal mixed-function oxidases. In conclusion, PCB is excreted primarily via the biliary route in rats. Excretion occurs both in the form of hydroxylated metabolites and as unchanged PCB, and the excretion rate is sensitive to the effects of an inducer or inhibitor of the hepatic microsomal hydroxylating enzymes.
Wosid WOS:A1974T653800040
Is Certified Translation No
Dupe Override No
Conference Location Washington, D.C.
Conference Name Thirteenth Annual Meeting of the Society of Toxicology
Conference Date March 10–14, 1974
Is Public Yes
Language Text English
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  • Is part of a larger document: 3378179