Determining source strength of semivolatile organic compounds using measured concentrations in indoor dust

Shin, HM; Mckone, TE; Nishioka, MG; Fallin, MD; Croen, LA; Hertz-Picciotto, I; Newschaffer, CJ; Bennett, DH

HERO ID

2215665

Reference Type

Journal Article

Year

2014

Language

English

PMID

24118221

HERO ID 2215665
In Press No
Year 2014
Title Determining source strength of semivolatile organic compounds using measured concentrations in indoor dust
Authors Shin, HM; Mckone, TE; Nishioka, MG; Fallin, MD; Croen, LA; Hertz-Picciotto, I; Newschaffer, CJ; Bennett, DH
Journal Indoor Air
Volume 24
Issue 3
Page Numbers 260-271
Abstract Consumer products and building materials emit a number of semivolatile organic compounds (SVOCs) in the indoor environment. Because indoor SVOCs accumulate in dust, we explore the use of dust to determine source strength and report here on analysis of dust samples collected in 30 U.S. homes for six phthalates, four personal care product ingredients, and five flame retardants. We then use a fugacity-based indoor mass-balance model to estimate the whole house emission rates of SVOCs that would account for the measured dust concentrations. Di-2-ethylhexyl phthalate (DEHP) and di-iso-nonyl phthalate (DiNP) were the most abundant compounds in these dust samples. On the other hand, the estimated emission rate of diethyl phthalate (DEP) is the largest among phthalates, although its dust concentration is over two orders of magnitude smaller than DEHP and DiNP. The magnitude of the estimated emission rate that corresponds to the measured dust concentration is found to be inversely correlated with the vapor pressure of the compound, indicating that dust concentrations alone cannot be used to determine which compounds have the greatest emission rates. The combined dust-assay modeling approach shows promise for estimating indoor emission rates for SVOCs.
Doi 10.1111/ina.12070
Pmid 24118221
Wosid WOS:000335008300005
Url http://dx.doi.org/10.1111/ina.12070
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Personal care products; Flame retardants; Emission rates; Dust; Phthalates; Modeling
Is Peer Review Yes
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