Synthesis, Structure and Luminescence of a Z(II) Complex Derived from 1,2-Benzenedicarboxylic Acid Ligand
Sun Jie; Wang Ai-Yun; Li Qing; Zhou Ju-Hua
| HERO ID | 3072217 |
|---|---|
| In Press | No |
| Year | 2015 |
| Title | Synthesis, Structure and Luminescence of a Z(II) Complex Derived from 1,2-Benzenedicarboxylic Acid Ligand |
| Authors | Sun Jie; Wang Ai-Yun; Li Qing; Zhou Ju-Hua |
| Journal | Chinese Journal of Structural Chemistry |
| Volume | 34 |
| Issue | 10 |
| Page Numbers | 1533-1538 |
| Abstract | The reaction of 1,2-benzenedicarboxylic acid (H2L) with Zn(NO)(3)center dot 6H(2)O and self-designed 1,2-bis(imidazol-1-ylmethyl)-benzene) (2-bimb) in DMA/H2O results in the forming of double chains Zn-II complex, {[Zn-2.5(L)(2)(bimb)(H2O)]center dot H2O}(n) (1), which has been characterized by TGA, PXRD and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group P (1) over bar with a = 11.4030(3), b = 11.9722(3), c = 13.5702(4) angstrom, alpha = 89.903(3), beta = 80.692(2), gamma = 63.999(3)degrees, C64H56N8O20Zn5, M-r = 1584.01, V= 1638.15(9) angstrom(3), Z = 1, D-c = 1.606 g center dot cm(-3), mu = 1.885 mm(-1), F(000) = 806., 2.07<theta<25 degrees, lambda(MoK alpha) = 0.71073 angstrom, T= 293(2) K, the final R = 0.0439, wR = 0.01393 and S = 1.057. X-ray diffraction analysis reveals that complex 1 possesses a 2D double-chain structure. In addition, the solid state luminescent property of complex 1, H2L, and 2-bimb at room temperature are also investigated. |
| Doi | 10.14102/j.cnki.0254-5861.2011-0761 |
| Wosid | WOS:000364610700010 |
| Url | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84946571925&doi=10.14102%2fj.cnki.0254-5861.2011-0761&partnerID=40&md5=32354940903173ebf32534761c15d33e |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal: Jiegou Huaxue ISSN: |
| Is Public | Yes |
| Language Text | English |
| Keyword | zinc complex; crystal structure; chain; luminescence |