Analysis of N-nitrosodiethylamine by ion chromatography coupled with UV photolysis pretreatment

Li, X; He, X; Dong, Y; Jia, L; He, Q

HERO ID

3475044

Reference Type

Journal Article

Year

2016

Language

English

PMID

28911584

HERO ID 3475044
In Press No
Year 2016
Title Analysis of N-nitrosodiethylamine by ion chromatography coupled with UV photolysis pretreatment
Authors Li, X; He, X; Dong, Y; Jia, L; He, Q
Journal Journal of Food and Drug Analysis
Volume 24
Issue 2
Page Numbers 311-315
Abstract Nitrosamines such as N-nitrosodiethylamine (NDEA) are commonly detected by spectrophotometry after photolysis and Griess reaction (PG) in food industries for lower cost. Results of this research indicate that NDEA decays rapidly under UV irradiation, and concentrations of the generated NO2- and NO3- ions vary with photolysis conditions. Thus, the measurement of the PG method may be inconsistent because it is based on the amount of photoproduced NO2-. In addition, more errors may be present in the PG method since NO3- cannot be measured colorimetrically using Griess reagent. In this work, the sum of the concentrations of photoproduced NO2- and NO3- was found to be equivalent to the initial NDEA before photolysis, and a photolysis ion chromatography method was validated, which may serve as a feasible and accurate method to determine nitrosamines. Copyright (C) 2015, Food and Drug Administration, Taiwan. Published by Elsevier Taiwan LLC. This is an open access article under the CC BY-NC-ND license.
Doi 10.1016/j.jfda.2015.10.0136
Pmid 28911584
Wosid WOS:000387936800010
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword ion chromatography; nitrosamine; nitrosodiethylamine; photolysis