Dermal absorption and urinary elimination of N-methyl-2-pyrrolidone

Bader, M; Keener, SA; Wrbitzky, R

HERO ID

3539719

Reference Type

Journal Article

Year

2005

Language

English

PMID

16001206

HERO ID 3539719
In Press No
Year 2005
Title Dermal absorption and urinary elimination of N-methyl-2-pyrrolidone
Authors Bader, M; Keener, SA; Wrbitzky, R
Journal International Archives of Occupational and Environmental Health
Volume 78
Issue 8
Page Numbers 673-676
Abstract <strong>OBJECTIVES: </strong>The dermal absorption of the solvent N-methyl-2-pyrrolidone (NMP) and its elimination in urine was investigated in an experimental study.<br /><br /><strong>METHODS: </strong>Seven volunteers were exposed to 1045 mg of liquid NMP under occlusive conditions for 2 h. Urine was collected before, during and up to 72 h after the exposure and analysed for NMP by GC/MS after liquid-liquid extraction. Additionally, the remaining NMP in the pads was determined to estimate the total dermal uptake.<br /><br /><strong>RESULTS: </strong>The concentration of NMP in urine increased rapidly after beginning of the exposure up to 1 h after the exposure was completed. A peak concentration of 1,836+/-863 microg/l was observed, the half-life in urine was 3.2 h. About 0.5% of the absorbed dose was excreted metabolically unchanged. An average dermal absorption of 5.5 mg cm(-2) h(-1) was calculated.<br /><br /><strong>CONCLUSIONS: </strong>The results of this study show that the percutaneous absorption of NMP may contribute significantly to the overall uptake of the solvent, e.g. in the workplace. Therefore, a biological monitoring of NMP exposed workers is essential for occupational-medical surveillance.
Doi 10.1007/s00420-005-0008-0
Pmid 16001206
Wosid WOS:000232779200010
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English