Fluorescent polymer made from chemical modification of poly(styrene-co-maleic anhydride)

Wang, KC; Huang, W; Xia, P; Gao, C; Yan, DY

HERO ID

3575930

Reference Type

Journal Article

Year

2002

Language

English

HERO ID 3575930
In Press No
Year 2002
Title Fluorescent polymer made from chemical modification of poly(styrene-co-maleic anhydride)
Authors Wang, KC; Huang, W; Xia, P; Gao, C; Yan, DY
Journal Reactive and Functional Polymers
Volume 52
Issue 3
Page Numbers 143-148
Abstract Poly(styrene-co-maleic anhydride) (SMA) was modified by commercially available fluorescent dye, 4-amino-N-(2,4-dimethylphenyl)-1,8-naphthalimide, to prepare fluorescent poly(styrene-co-maleimide) (SMI). FT-IR, UV-Vis and fluorescent spectra of this polymer were investigated. The polymer can emit strong yellow-green fluorescence (around 5 10 nm) and its thermal stability and solubility were improved. The number-averaged molecular weight (]U) measured by GPC was about 1.8X10(5) relative to the polystyrene standard and the molecular weight distribution was 1.86. The glass transition temperature (T-g) determined by differential scanning calorimeter (DSC) was 150.8 degreesC, and 17 degreesC higher than the T. (133.7 degreesC) of SMA. The influences of solvent, concentration and quencher on the fluorescent behaviors of SMI are discussed too. (C) 2002 Elsevier Science B.V. All rights reserved.
Doi 10.1016/S1381-5148(02)00088-3
Wosid WOS:000177693000004
Url https://www.scopus.com/inward/record.uri?eid=2-s2.0-0036722999&doi=10.1016%2fS1381-5148%2802%2900088-3&partnerID=40&md5=2d22b412a295418e7b6db96ebcbb67ff
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword fluorescent polymer; chemical modification; SMA