Two functional [2]rotaxanes featuring efficient intercomponent interactions between chromophores
Yao, J; Fu, Xin; Zheng, XiuLi; Cao, ZQi; Qu, DaHui
| HERO ID | 3575984 |
|---|---|
| In Press | No |
| Year | 2015 |
| Title | Two functional [2]rotaxanes featuring efficient intercomponent interactions between chromophores |
| Authors | Yao, J; Fu, Xin; Zheng, XiuLi; Cao, ZQi; Qu, DaHui |
| Journal | Dyes and Pigments |
| Volume | 121 |
| Page Numbers | 13-20 |
| Abstract | Two functional [2]rotaxanes, with a 4-morpholin-naphthalimide fluorophore as one of the two stoppers and a difluoroboradiaza-s-indacene functionalized dibenzo[24]crown-8 as macrocycle, were designed, synthesized and well characterized. [2]Rotaxane 1 and 2 had almost the same structural skeleton, and a ferrocene unit was introduced in [2]rotaxane 1 as the other stopper, while a 3,5-dimethoxybenzene stopper in [2]rotaxane 2. It has shown that efficient energy transfer process in both two [2]rotaxanes occurred from the 4-morpholin-naphthalimide donor to the difluoroboradiaza-s-indacene acceptor. Moreover, [2]rotaxane 1 exhibited a remarkable fluorescence increase in response to the addition of base that can drive the shuttling motion because of the introduction of ferrocene electron donor. This work can pave the way for the design and construction of complex and functional molecular systems based on the mechanically interlocked molecules. (C) 2015 Elsevier Ltd. All rights reserved. |
| Doi | 10.1016/j.dyepig.2015.05.005 |
| Wosid | WOS:000358808400003 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Energy transfer; Rotaxane; Click chemistry; Photoinduced electron transfer; Fluorophore; Ferrocene |