Optically active perfluoro-2-propoxypropionic acid: A new chiral reagent for 19F NMR study
Kawa, H; Yamaguchi, F; Ishikawa, N
| HERO ID | 3859945 |
|---|---|
| In Press | No |
| Year | 1982 |
| Title | Optically active perfluoro-2-propoxypropionic acid: A new chiral reagent for 19F NMR study |
| Authors | Kawa, H; Yamaguchi, F; Ishikawa, N |
| Journal | Journal of Fluorine Chemistry |
| Volume | 20 |
| Issue | 4 |
| Page Numbers | 475-485 |
| Abstract | Perfluoro-2-propoxypropionic acid, which was prepared by the anionic dimerization of hexafluoro-1,2-epoxypropane, was optically resolved via diastereomeric salt formation with chiral amines. The optically pure (+) and (−) perfluoro-2-propoxypropionic acids thus obtained were found to be a convenient chiral reagent for determining enantiomeric compositions of α-amino acids by means of 19F nmr analysis. |
| Doi | 10.1016/S0022-1139(00)82273-3 |
| Wosid | WOS:A1982NV76700004 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |