Preparation and electrochemical properties of Ba0.8La0.2FeO3-delta cathode for intermediate-temperature solid oxide fuel cells

Liu, P; Zhu, H; Kong, J; Wei, N; Wang, Can; Yang, X; Liu, Q

HERO ID

4132177

Reference Type

Journal Article

Year

2017

HERO ID 4132177
In Press No
Year 2017
Title Preparation and electrochemical properties of Ba0.8La0.2FeO3-delta cathode for intermediate-temperature solid oxide fuel cells
Authors Liu, P; Zhu, H; Kong, J; Wei, N; Wang, Can; Yang, X; Liu, Q
Journal Journal of Sol-Gel Science and Technology
Volume 82
Issue 1
Page Numbers 233-238
Abstract Perovskite Ba0.8La0.2FeO3-delta was synthesized via a glycine-nitrate process as the cathode material for intermediate-temperature solid oxide fuel cells. Ultra-fine pure phase Ba0.8La0.2FeO3-delta powder was obtained after the self-propagating combustion of a complex xerogel precursor. The Ba0.8La0.2FeO3-delta cathode showed good compatibility and an enhanced phase interface with a samarium-doped ceria electrolyte. Electrochemical measurements showed that the Ba0.8La0.2FeO3-delta cathode achieved a low polarization resistance of 0.58 Omega cm(2) at 800 A degrees C in an air atmosphere. The porous nanostructure guaranteed the catalytic activity for the oxygen reduction reaction, even if the cathode material possessed a cobalt-free and low rare earth composition. <br> <br>[GRAPHICS] <br> <br>.
Doi 10.1007/s10971-016-4300-0
Wosid WOS:000398948200027
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword Intermediate-temperature solid oxide fuel cells; Lanthanum-doped barium ferrite; Cathode; Glycine-nitrate process; Electrochemical properties