Study of Electrochemical Sensor for Nitrite Based on Composites of Zirconium Dioxide Nanoparticles/Reduced Graphene Oxide

Shan Duo-Liang; Wang Yong-Lan; Wang Yan-Feng; Lu Xiao-Quan

HERO ID

4132609

Reference Type

Journal Article

Year

2017

HERO ID 4132609
In Press No
Year 2017
Title Study of Electrochemical Sensor for Nitrite Based on Composites of Zirconium Dioxide Nanoparticles/Reduced Graphene Oxide
Authors Shan Duo-Liang; Wang Yong-Lan; Wang Yan-Feng; Lu Xiao-Quan
Journal Chinese Journal of Analytical Chemistry / Fen Xi Hua Xue
Volume 45
Issue 4
Page Numbers 502-507
Abstract A nitrite electrochemical sensor based on electrodeposition of zirconium dioxide nanoparticles on reduced graphene oxide modified electrode was successfully constructed for the detection of nitrite. The electrochemical behavior of the modified electrode was investigated by cyclic voltammetry and amperometric i-t curve. Under the optimal conditions, the amperometric i-t curve response of the electrode showed a linear relationship with nitrite concentration in the range of 3. 0. 10(-7) - 1. 0 x 10(-6) mol/L and 1. 0 x 10(-6) - 6. 0 x 10(-6) mol/L, and the detection limit was 1. 0 x 10(-7) mol/L (S/N = 3). The fabricated sensor exhibited high sensitivity, good stability and high reproducibility. This sensor was applied for the detection of nitrite in sausage samples with favorable recoveries of 93. 7% - 110. 4% and relative standard deviation (RSD) of 1. 6% - 2. 1%.
Doi 10.11895/j.issn.0253-3820.160775
Wosid WOS:000401835600004
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword Zirconia; Reduced graphene oxide; Nitrite; Electrochemical sensor