Silver(I) thiosemicarbazone complex [Ag(catsc)(PPh3)(2)]NO3: Synthesis, characterization, crystal structure, and antibacterial study
Khalaji, AD; Shahsavani, E; Feizi, N; Kucerakova, M; Dusek, M; Mazandarani, R
| HERO ID | 4132670 |
|---|---|
| In Press | No |
| Year | 2017 |
| Title | Silver(I) thiosemicarbazone complex [Ag(catsc)(PPh3)(2)]NO3: Synthesis, characterization, crystal structure, and antibacterial study |
| Authors | Khalaji, AD; Shahsavani, E; Feizi, N; Kucerakova, M; Dusek, M; Mazandarani, R |
| Journal | Academie des Sciences. Comptes Rendus. Chimie |
| Volume | 20 |
| Issue | 5 |
| Page Numbers | 534-539 |
| Abstract | We report the synthesis, characterization and crystal structure of a new mononuclear silver(I) complex, [Ag(catsc)(PPh3)(2)]NO3 (catsc = 3-phenylpropenalthiosemicarbazone). The complex was prepared by the reaction of catsc and AgNO3 in the presence of PPh3 and characterized by elemental analysis (CHN), FFIR, H-1, C-13 and P-31 NMR spectroscopy, and single-crystal X-ray diffraction. In the complex, catsc acts as a bidentate NS ligand while the nitrate is a counter ion. The silver ion is coordinated by a bidentate ligand and two PPh3 in the form of a distorted tetrahedron. In addition, the antibacterial effect of the complex was studied against the standard strains of two gram-positive (Staphylococcus aureus and Enterococcus faecalis) and two gram-negative (Escherichia coli and Pseudomonas aeruginosa) bacteria. (C) 2016 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved. |
| Doi | 10.1016/j.crci.2016.09.001 |
| Wosid | WOS:000412865500010 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Silver(I) complex; Single-crystal; Antibacterial effect; Tetrahedral; Bidentate |