Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(iv)-oxo complexes
Lee, YM; Yoo, M; Yoon, H; Li, XX; Nam, W; Fukuzumi, S
| HERO ID | 4269007 |
|---|---|
| In Press | No |
| Year | 2017 |
| Title | Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(iv)-oxo complexes |
| Authors | Lee, YM; Yoo, M; Yoon, H; Li, XX; Nam, W; Fukuzumi, S |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue | 67 |
| Page Numbers | 9352-9355 |
| Abstract | Direct oxygen atom transfer from a nonheme Mn(iv)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, to triphenylphosphine (Ph3P) derivatives occurs with a significant steric effect resulting from the ortho-substituents on the phenyl group of the Ph3P derivatives, whereas the phosphine oxygenation by a Mn(iv)-oxo complex in the presence of HOTf occurs via an electron transfer mechanism without the substrate-steric effect. |
| Doi | 10.1039/c7cc04035k |
| Pmid | 28786444 |
| Wosid | WOS:000407808000015 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |