HOMOGENEOUS-CATALYTIC ACETOXYLATION OF 1-HEXENE AND CYCLOHEXENE
Trushova, NV; Devekki, AV
| HERO ID | 4684045 |
|---|---|
| In Press | No |
| Year | 1992 |
| Title | HOMOGENEOUS-CATALYTIC ACETOXYLATION OF 1-HEXENE AND CYCLOHEXENE |
| Authors | Trushova, NV; Devekki, AV |
| Journal | Petroleum Chemistry |
| Volume | 32 |
| Issue | 4 |
| Page Numbers | 313-319 |
| Abstract | A study has been made of the acetoxylation of 1-hexene and cyclohexene in the presence of PdCl42- and a nitrate-iodate reoxidative system ensuring high yields of the corresponding acetoxyalkanes. It has been established that a binuclear pi-olefinic bridge-type palladium complex is a catalytically active particle. It is assumed that the mechanisms of formation of 1,2-hexanediol monoacetate and diacetoxycyclohexane differ at the final stage of transformation of the acetoxonium ion. Acetoxylation is retarded by the reaction products, which screen the coordination sphere of palladium. |
| Wosid | WOS:A1992KE92200011 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |