VOLUME AND HEAT-CAPACITY OF MODEL NONAQUEOUS SELF-ASSEMBLY SYSTEMS
Perron, G; Cote, JF; Lambert, D; Pageau, J; Desnoyers, JE
| HERO ID | 4684067 |
|---|---|
| In Press | No |
| Year | 1994 |
| Title | VOLUME AND HEAT-CAPACITY OF MODEL NONAQUEOUS SELF-ASSEMBLY SYSTEMS |
| Authors | Perron, G; Cote, JF; Lambert, D; Pageau, J; Desnoyers, JE |
| Journal | Journal of Solution Chemistry |
| Volume | 23 |
| Issue | 2 |
| Page Numbers | 121-133 |
| Abstract | Blends of immiscible polymers are often stabilized by block copolymers which can form non-aqueous micelles and microemulsions in the liquid polymers. The phase diagrams, apparent volumes and apparent heat capacities of model non-aqueous binary and ternary systems were studied in order to investigate the conditions under which such self-assembly systems could form. 1,2-Hexanediol, which can cosolubilize hexane and ethyleneglycol forms inverse micelles in hexane and weak microaggregates in ethyleneglycol. Genapol X-060, a commercial alcoholic surfactant containing on the average an aliphatic chain of 13 carbons and 6 oxyethylenes (C13E6), forms microaggregates in poly(ethyleneglycol) 400. Them self-assembly systems are strengthen in the presence of a third component which has an affinity for the inner phase. |
| Doi | 10.1007/BF00973541 |
| Wosid | WOS:A1994NB50800003 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | PHASE DIAGRAMS; VOLUME; HEAT CAPACITY; NONAQUEOUS MICELLE; NONAQUEOUS MICROEMULSION; MIXTURES OF 1,2-HEXANEDIOL, ETHYLENEGLYCOL AND HEXANE; MIXTURES OF GENAPOL X-060, DECANE AND POLY(ETHYLENEGLYCOL)-400 |