Direct labeling of antibodies IgG with rhenium-186 using sodium glucoheptonate

Zhu, ZH; Wu, YH; Zhang, ZY; Liu, YF

HERO ID

4850268

Reference Type

Journal Article

Year

1997

HERO ID 4850268
In Press No
Year 1997
Title Direct labeling of antibodies IgG with rhenium-186 using sodium glucoheptonate
Authors Zhu, ZH; Wu, YH; Zhang, ZY; Liu, YF
Journal Radiochimica Acta
Volume 79
Issue 2
Page Numbers 105-108
Abstract In the direct labeling of antibodies with Re-186, 188, the lower redox potential of ReO4- than TcO4- requires the addition of excess SnCl2 and a medium-chelating agent for stabilizing the excess of SnCl2 in solution. Through extensive tests, sodium glucoheptonate (GH) was chosen as an excellent stabilizer for SnCl2 and also the reduced Re(V) from a variety of chelators, such as citrate, cyclodextrin, tartrate, inositol, glucose, glycine, etc. ReO4- solution was then quantitatively reduced for 2 h with newly prepared SnCl2(GH) solution. Then, we directly incorporated the reduced Re to the antibodies IgG modified with 135 ford of NaHSO3 and 3500 fold of 2-ME, and more than 90% of specific binding was yielded in 100-150 min at room temperature. TLC analysis indicated that less than 5% of activity was in the colloid form. Radiolabeled antibodies IgG were stable to the challenging of 700 fold of DTPA, and also showed fine in vivo stability.
Wosid WOS:000071986100008
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword rhenium-186; direct labeling; IgG; sodium glucoheptonate; stabilizer; transchelation agent