Enantioselective allylic substitution catalyzed by Pd-ferrocenylphosphine complexes in [bmim][PF] ionic liquid
Toma, S; Gotov, B; Kmentova, I; Solcaniova, Eva
| HERO ID | 4933000 |
|---|---|
| In Press | No |
| Year | 2000 |
| Title | Enantioselective allylic substitution catalyzed by Pd-ferrocenylphosphine complexes in [bmim][PF] ionic liquid |
| Authors | Toma, S; Gotov, B; Kmentova, I; Solcaniova, Eva |
| Journal | Green Chemistry |
| Volume | 2 |
| Issue | 4 (2000) |
| Page Numbers | 149-151 |
| Abstract | Enantioselective allylic substitution reactions of ()-()-1,3-diphenyl-3-acetoxyprop-1-ene with dimethyl malonate (DMM) are studied in 1-butyl-3-methylimidazolinium hexafluorophosphate ([bmim][PF]) as an ionic solvent; the reactions are catalyzed by Pd complexes of two homochiral ferrocenylphosphine ligands, ()-BPPFA and ()-BPPFDEA with the recycling of the catalytic system being tested. A similar reaction with 1-phenyl-3-acetoxyprop-1-ene is also studied with only a linear achiral product being isolated. |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Solvents; green development; Recycling; Waste management |