Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines
Namba, K; Kanaki, M; Suto, H; Nishizawa, M; Tanino, K
| HERO ID | 5415208 |
|---|---|
| In Press | No |
| Year | 2012 |
| Title | Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines |
| Authors | Namba, K; Kanaki, M; Suto, H; Nishizawa, M; Tanino, K |
| Journal | Organic Letters |
| Volume | 14 |
| Issue | 5 |
| Page Numbers | 1222-1225 |
| Abstract | An efficient method for the construction of dihydroquinoline derivatives possessing a quaternary carbon center is developed by an application of Hg(OTf)(2)-catalyzed vinylogous semi-pinacol-type rearrangement. The reaction was found to be specifically catalyzed by mercury salt and to proceed via a bicyclic aminal. |
| Doi | 10.1021/ol2034492 |
| Pmid | 22339178 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |