Direct sulfonation of methane to methanesulfonic acid with SO2 using Ca salts as promoters
Mukhopadhyay, S; Bell, AT
| HERO ID | 5416728 |
|---|---|
| In Press | No |
| Year | 2003 |
| Title | Direct sulfonation of methane to methanesulfonic acid with SO2 using Ca salts as promoters |
| Authors | Mukhopadhyay, S; Bell, AT |
| Journal | Journal of the American Chemical Society |
| Volume | 125 |
| Issue | 15 |
| Page Numbers | 4406-4407 |
| Abstract | Direct liquid-phase sulfonation of methane to methanesulfonic acid (MSA) with SO2 has been achieved in triflic acid using K2S2O8 as the oxidant and a small amount of a Ca salt as the promoter. The effects of reaction conditions on the conversion of SO2 to MSA were examined. Included were the influence of solvent acidity, reaction duration, reaction temperature, amount of K2S2O8, and composition and amount of promoters. |
| Doi | 10.1021/ja0281737 |
| Pmid | 12683795 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |