Biodiesel synthesis combining pre-esterification with alkali catalyzed process from rapeseed oil deodorizer distillate
Liu, Y; Wang, L; Yan, Y
| HERO ID | 612513 |
|---|---|
| In Press | No |
| Year | 2009 |
| Title | Biodiesel synthesis combining pre-esterification with alkali catalyzed process from rapeseed oil deodorizer distillate |
| Authors | Liu, Y; Wang, L; Yan, Y |
| Journal | Fuel Processing Technology |
| Volume | 90 |
| Issue | 7/8 |
| Page Numbers | 857-862 |
| Abstract | Abstract: A two-step technique combining pre-esterification catalyzed by cation exchange resin with transesterification catalyzed by base alkali was developed to produce biodiesel from rapeseed oil deodorizer distillate (RDOD). The free fatty acids (FFAs) in the feedstock were converted to methyl esters in the pre-esterification step using a column reactor packed with cation exchange resin. The acid value of oil was reduced from the initial 97.60 mg-KOH g<sup>−1</sup> oil to 1.12 mg-KOH g<sup>−1</sup> oil under the conditions of cation exchange resin D002 catalyst packed dosage 18 wt.% (based on oil weight), oil to methanol molar ratio 1:9, reaction temperature 60 °C, and reaction time 4 h. The biodiesel yield by transesterification was 97.4% in 1.5 h using 0.8 wt.% KOH as catalyst and a molar ratio of oil to methanol 1:4 at 60 °C. The properties of RDOD biodiesel production in a packed column reactor followed by KOH catalyzed transesterification were measured up the standards of EN14214 and ASTM6751-03. [Copyright 2009 Elsevier] Copyright of Fuel Processing Technology is the property of Elsevier Science Publishers B.V. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Doi | 10.1016/j.fuproc.2009.04.005 |
| Wosid | WOS:000267692600002 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | BIODIESEL fuels; FATTY acids; RAW materials; ANIMAL products |
| Is Qa | No |