Fabrication of superhydrophobic polymethylsilsesquioxane nanostructures on cotton textiles by a solution-immersion process

Shirgholami, MA; Shateri Khalil-Abad, M; Khajavi, R; Yazdanshenas, ME

HERO ID

737703

Reference Type

Journal Article

Year

2011

Language

English

PMID

21536303

HERO ID 737703
In Press No
Year 2011
Title Fabrication of superhydrophobic polymethylsilsesquioxane nanostructures on cotton textiles by a solution-immersion process
Authors Shirgholami, MA; Shateri Khalil-Abad, M; Khajavi, R; Yazdanshenas, ME
Journal Journal of Colloid and Interface Science
Volume 359
Issue 2
Page Numbers 530-535
Abstract Superhydrophobic cotton textiles are prepared by a simple, one-step and inexpensive phase separation method under ambient conditions by which a layer of polymethylsilsesquioxane (PMSQ) nanostructures is covered onto the cellulose fibers. By changing the silane precursor concentration, PMSQ nanostructures with various shapes, morphologies and sizes were fabricated. Nanostructures were characterized using SEM, EDS, and attenuated total reflectance FTIR. The wettability of the modified cellulose surfaces was characterized with contact-angle goniometry and sliding angle technique, respectively. The water contact angle of modified cotton is measured to be higher than 150°, which is high enough to exhibit the lotus effect as a result of the superhydrophobicity. Tunable water-repellent properties of the fabric are also demonstrated, with sliding contact angles varying from "sticky" to "slippery" depending upon different nanostructures on the surface of the fibers. It is expected that this simple technique will accelerate the large-scale production of superhydrophobic cellulosic materials with new industrial applications.
Doi 10.1016/j.jcis.2011.04.031
Pmid 21536303
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Language Text English
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