Comparison of ozone-specific (OZAC) and oxygen radical (ORAC) antioxidant capacity assays for use with nasal lavage fluid

Rutkowski, JM; Santiag, LY; Ben-Jebria, A; Ultman, JS

HERO ID

749268

Reference Type

Journal Article

Year

2011

Language

English

PMID

21513792

HERO ID 749268
In Press No
Year 2011
Title Comparison of ozone-specific (OZAC) and oxygen radical (ORAC) antioxidant capacity assays for use with nasal lavage fluid
Authors Rutkowski, JM; Santiag, LY; Ben-Jebria, A; Ultman, JS
Journal Toxicology In Vitro
Volume 25
Issue 7
Page Numbers 1406-1413
Abstract Antioxidants in respiratory mucus protect the underlying airway epithelium from damage by ozone (O(3)), a common outdoor air pollutant. To understand O(3)-antioxidant interactions and the variation of these interactions among individuals, in vitro assays are needed to measure the total antioxidant capacity of airway lavage fluid, a convenient source of (diluted) mucous samples. Here, we compare the oxygen radical absorbance capacity (ORAC), a general method that uses peroxyl radicals as a reactive substance, to the recently developed ozone specific antioxidant capacity (OZAC), a procedure that directly employs O(3). For prepared model mucous antioxidant solutions containing uric acid, ascorbic acid or glutathione, the ORAC and OZAC methods yielded comparable antioxidant capacities. The addition of EDTA or DETAPAC, necessary to prevent auto-oxidation of test solutions during the ORAC assay, unpredictably altered ORAC measurements. EDTA did not have a significant effect on OZAC measurements in either prepared uric acid or ascorbic acid solutions. When assessing antioxidant capacities of nasal lavage samples, the ORAC and OZAC assays were no longer comparable. Because the OZAC of nasal lavage samples was positively related to measured uric acid concentrations whereas the ORAC data were not, the OZAC method appears to provide more realistic mucous antioxidant capacities than the ORAC method.
Doi 10.1016/j.tiv.2011.04.008
Pmid 21513792
Wosid WOS:000295066600021
Url https://linkinghub.elsevier.com/retrieve/pii/S0887233311000890
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
Keyword Uric acid; Ascorbic acid; Glutathione; Chelating agents; Ozone inhalation; Air pollutant
Is Qa No