Densities and Volumetric Properties of Binary Mixtures of Butyl Acrylate with Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene at Temperatures from 288.15 K to 318.15 K
Nain, AK; Sharma, R; Ali, A; Gopal, S
| HERO ID | 856244 |
|---|---|
| In Press | No |
| Year | 2010 |
| Title | Densities and Volumetric Properties of Binary Mixtures of Butyl Acrylate with Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene at Temperatures from 288.15 K to 318.15 K |
| Authors | Nain, AK; Sharma, R; Ali, A; Gopal, S |
| Journal | International Journal of Thermophysics |
| Volume | 31 |
| Issue | 6 |
| Page Numbers | 1073-1091 |
| Abstract | The densities, rho, of binary mixtures of butyl acrylate (BA) with benzene, toluene, o-xylene, m-xylene, p-xylene, and mesitylene, including those of pure liquids, over the entire composition range were measured at the temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and atmospheric pressure. From the experimental data, the excess molar volumes, V(m)(E) were calculated. The V(m)(E) values were negative over the whole composition range for all the mixtures and at each temperature studied, except for BA + mesitylene which exhibit positive V(m)(E) values, indicating the presence of specific interactions between BA and aromatic hydrocarbon molecules. The deviations in V(m)(E) values follow the order: benzene<toluene<p-xylene<m-xylene<o-xylene<mesitylene. It is observed that V(m)(E) values depend upon the number and position of the methyl groups in these aromatic hydrocarbons. |
| Doi | 10.1007/s10765-010-0768-y |
| Wosid | WOS:000283255500002 |
| Url | http://www.springerlink.com/index/10.1007/s10765-010-0768-y |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Aromatic hydrocarbons; Butyl acrylate; Density; Excess molar volume; Molecular interactions |
| Is Qa | No |