Influence of carbon nanotubes on pyrene bioaccumulation from contaminated soils by earthworms

Petersen, EJ; Pinto, RA; Landrum, PF; Weber, WJ

HERO ID

955015

Reference Type

Journal Article

Year

2009

Language

English

PMID

19569349

HERO ID 955015
In Press No
Year 2009
Title Influence of carbon nanotubes on pyrene bioaccumulation from contaminated soils by earthworms
Authors Petersen, EJ; Pinto, RA; Landrum, PF; Weber, WJ
Journal Environmental Science & Technology
Volume 43
Issue 11
Page Numbers 4181-4187
Abstract Increasing production of and application potentials for carbon nanotubes (CNTs) suggest these materials will enter soil and sediment ecosystems in significant masses in upcoming years. This may result in ecological risks, either from the presence of the CNTs themselves or, given their exceptional sorption capacities, from their effects on the fate and accumulation of concurrently present hydrophobic organic chemicals (HOCs). Here we test the influence of additions of single-walled CNTs (SWNTs) and multi-walled CNTs (MWNTs) to two different pyrene-contaminated soils on uptake of this HOC by earthworms (Eisenia foetida). The effects of nanotube additions to the soils were observed to be CNT concentration dependent, with 0.3 mg nanotubes per gram of soil having no impact, while 3.0 mg/g of SWNTs or MWNTs substantially decreased pyrene bioaccumulation from both contaminated soils. The presence of CNTs also affected pyrene elimination rates. After a 14-day exposure to pyrene-spiked soils, earthworms showed enhanced elimination rates in soils amended with 3.0 mg CNT/g but not 0.3 mg CNT/g. These results suggest that the presence of SWNTs or MWNTs in terrestrial ecosystems will have concentration-dependent effects on decreasing HOC accumulation by earthworms in a manner similar to that expected of most "hard" carbons.
Doi 10.1021/es803023a
Pmid 19569349
Wosid WOS:000266546700035
Url http://pubs.acs.org/doi/abs/10.1021/es803023a
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Dupe Override No
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Language Text English
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